Oxygen in CatalysisCRC Press, 29 nov. 1990 - 488 pages A description of catalytic systems commonly used as model systems in the laboratory and as industrial catalysts in large-scale operations, and a discussion of the mechanisms operating in these reactions. Attempts to describe the elementary steps by quantum chemical methods are also shown, as are rec |
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Expressions et termes fréquents
acid acrolein activation energy adsorbed adsorbed oxygen adsorption allyl allyl species anatase anion bands benzene Bielański bond Boreskov butadiene butene carbon monoxide Catal catalyst catalytic oxidation catalytic reaction cations centers Chem chemical chemisorbed chemisorption chemisorption of oxygen complex coordination coverage crystal crystallites curve decrease defects desorbed desorption dioxygen electron electrophilic ethylene oxide FIGURE formation function gas phase Haber heat hydrocarbon hydrogen increasing indicates interaction intermediate isotopic kcal kcal mol-1 Kinet lattice oxygen layer maleic anhydride mechanism molecular molecule MoO3 nucleophilic o-xylene observed obtained octahedra olefins orbitals oxidation of propene oxide catalysts oxide ions oxygen oxygen atoms oxygen ions oxygen species Phys plane platinum pressure propene reactant reaction rate reactor redox reduction reoxidation samples selective oxidation shown in Fig solid structure studies tetrahedra tetrahedral tion total oxidation transition metal transition metal oxides vacancies vanadia